1 | #*------------------------------------------------------------------- |
---|
2 | * EMSO Model Library (EML) Copyright (C) 2004 - 2007 ALSOC. |
---|
3 | * |
---|
4 | * This LIBRARY is free software; you can distribute it and/or modify |
---|
5 | * it under the therms of the ALSOC FREE LICENSE as available at |
---|
6 | * http://www.enq.ufrgs.br/alsoc. |
---|
7 | * |
---|
8 | * EMSO Copyright (C) 2004 - 2007 ALSOC, original code |
---|
9 | * from http://www.rps.eng.br Copyright (C) 2002-2004. |
---|
10 | * All rights reserved. |
---|
11 | * |
---|
12 | * EMSO is distributed under the therms of the ALSOC LICENSE as |
---|
13 | * available at http://www.enq.ufrgs.br/alsoc. |
---|
14 | * |
---|
15 | *---------------------------------------------------------------------- |
---|
16 | * Author: Paula B. Staudt |
---|
17 | * $Id: tray.mso 522 2008-05-21 23:21:12Z arge $ |
---|
18 | *--------------------------------------------------------------------*# |
---|
19 | |
---|
20 | using "streams"; |
---|
21 | |
---|
22 | Model trayBasicTeste |
---|
23 | ATTRIBUTES |
---|
24 | Pallete = false; |
---|
25 | Icon = "icon/Tray"; |
---|
26 | Brief = "Basic equations of a tray column model."; |
---|
27 | Info = |
---|
28 | "This model contains only the main equations of a column tray equilibrium model without |
---|
29 | the hidraulic equations. |
---|
30 | |
---|
31 | == Assumptions == |
---|
32 | * both phases (liquid and vapour) exists all the time; |
---|
33 | * thermodymanic equilibrium with Murphree plate efficiency; |
---|
34 | * no entrainment of liquid or vapour phase; |
---|
35 | * no weeping; |
---|
36 | * the dymanics in the downcomer are neglected. |
---|
37 | "; |
---|
38 | |
---|
39 | PARAMETERS |
---|
40 | outer PP as Plugin (Brief = "External Physical Properties", Type="PP"); |
---|
41 | outer NComp as Integer; |
---|
42 | |
---|
43 | VARIABLES |
---|
44 | |
---|
45 | Inlet as stream (Brief="Feed stream", PosX=0, PosY=0.4932, Symbol="_{in}"); |
---|
46 | in InletL as stream (Brief="Inlet liquid stream", PosX=0.5195, PosY=0, Symbol="_{inL}"); |
---|
47 | in InletV as stream (Brief="Inlet vapour stream", PosX=0.4994, PosY=1, Symbol="_{inV}"); |
---|
48 | out OutletL as liquid_stream (Brief="Outlet liquid stream", PosX=0.8277, PosY=1, Symbol="_{outL}"); |
---|
49 | out OutletV as vapour_stream (Brief="Outlet vapour stream", PosX=0.8043, PosY=0, Symbol="_{outV}"); |
---|
50 | |
---|
51 | M(NComp) as mol (Brief="Molar Holdup in the tray"); |
---|
52 | ML as mol (Brief="Molar liquid holdup"); |
---|
53 | MV as mol (Brief="Molar vapour holdup"); |
---|
54 | E as energy (Brief="Total Energy Holdup on tray"); |
---|
55 | vL as volume_mol (Brief="Liquid Molar Volume"); |
---|
56 | vV as volume_mol (Brief="Vapour Molar volume"); |
---|
57 | Level as length (Brief="Height of clear liquid on plate"); |
---|
58 | yideal(NComp) as fraction; |
---|
59 | |
---|
60 | |
---|
61 | EQUATIONS |
---|
62 | "Component Molar Balance" |
---|
63 | diff(M)=Inlet.F*Inlet.z + InletL.F*InletL.z + InletV.F*InletV.z- OutletL.F*OutletL.z - OutletV.F*OutletV.z; |
---|
64 | |
---|
65 | "Molar Holdup" |
---|
66 | M = ML*OutletL.z + MV*OutletV.z; |
---|
67 | |
---|
68 | "Mol fraction normalisation" |
---|
69 | sum(OutletL.z)= 1.0; |
---|
70 | sum(OutletL.z)= sum(OutletV.z); |
---|
71 | |
---|
72 | "Liquid Volume" |
---|
73 | vL = PP.LiquidVolume(OutletL.T, OutletL.P, OutletL.z); |
---|
74 | |
---|
75 | "Vapour Volume" |
---|
76 | vV = PP.VapourVolume(OutletV.T, OutletV.P, OutletV.z); |
---|
77 | |
---|
78 | "Chemical Equilibrium" |
---|
79 | PP.LiquidFugacityCoefficient(OutletL.T, OutletL.P, OutletL.z)*OutletL.z = PP.VapourFugacityCoefficient(OutletV.T, OutletV.P, yideal)*yideal; |
---|
80 | |
---|
81 | "Thermal Equilibrium" |
---|
82 | OutletV.T = OutletL.T; |
---|
83 | |
---|
84 | "Mechanical Equilibrium" |
---|
85 | OutletV.P = OutletL.P; |
---|
86 | |
---|
87 | end |
---|
88 | |
---|
89 | Model trayTeste as trayBasicTeste |
---|
90 | ATTRIBUTES |
---|
91 | Pallete = false; |
---|
92 | Icon = "icon/Tray"; |
---|
93 | Brief = "Complete model of a column tray."; |
---|
94 | Info = |
---|
95 | "== Specify == |
---|
96 | * the Feed stream |
---|
97 | * the Liquid inlet stream |
---|
98 | * the Vapour inlet stream |
---|
99 | * the Vapour outlet flow (OutletV.F) |
---|
100 | |
---|
101 | == Initial == |
---|
102 | * the plate temperature (OutletL.T) |
---|
103 | * the liquid height (Level) OR the liquid flow OutletL.F |
---|
104 | * (NoComps - 1) OutletL compositions |
---|
105 | |
---|
106 | == Options == |
---|
107 | You can choose the equation for the liquid outlet flow and the vapour |
---|
108 | inlet flow calculation through the VapourFlowModel and LiquidFlowModel |
---|
109 | switchers. |
---|
110 | |
---|
111 | == References == |
---|
112 | * ELGUE, S.; PRAT, L.; CABASSUD, M.; LANN, J. L.; CéZERAC, J. Dynamic models for start-up operations of batch distillation columns with experimental validation. Computers and Chemical Engineering, v. 28, p. 2735-2747, 2004. |
---|
113 | * FEEHERY, W. F. Dynamic Optimization with Path Constraints. Tese (Doutorado) - Massachusetts Institute of Technology, June 1998. |
---|
114 | * KLINGBERG, A. Modeling and Optimization of Batch Distillation. Dissertação (Mestrado) - Department of Automatic Control, Lund Institute of Technology, Lund, Sweden, fev. 2000. |
---|
115 | * OLSEN, I.; ENDRESTOL, G. O.; SIRA, T. A rigorous and efficient distillation column model for engineering and training simulators. Computers and Chemical Engineering,v. 21, n. Suppl, p. S193-S198, 1997. |
---|
116 | * REEPMEYER, F.; REPKE, J.-U.; WOZNY, G. Analysis of the start-up process for reactive distillation. Chemical Engineering Technology, v. 26, p. 81-86, 2003. |
---|
117 | * ROFFEL, B.; BETLEM, B.; RUIJTER, J. de. First principles dynamic modeling and multivariable control of a cryogenic distillation column process. Computers and Chemical Engineering, v. 24, p. 111-123, 2000. |
---|
118 | * WANG, L.; LI, P.; WOZNY, G.; WANG, S. A start-up model for simulation of batch distillation starting from a cold state. Computers and Chemical Engineering, v. 27, p.1485-1497, 2003. |
---|
119 | "; |
---|
120 | |
---|
121 | VARIABLES |
---|
122 | rhoL as dens_mass; |
---|
123 | rhoV as dens_mass; |
---|
124 | |
---|
125 | btemp as Real (Brief="Temporary variable of Roffels liquid flow equation"); |
---|
126 | |
---|
127 | EQUATIONS |
---|
128 | |
---|
129 | "Liquid Density" |
---|
130 | rhoL = PP.LiquidDensity(OutletL.T, OutletL.P, OutletL.z); |
---|
131 | |
---|
132 | "Vapour Density" |
---|
133 | rhoV = PP.VapourDensity(InletV.T, InletV.P, InletV.z); |
---|
134 | |
---|
135 | end |
---|
136 | |
---|
137 | #*------------------------------------------------------------------- |
---|
138 | * Model of a tray with reaction |
---|
139 | *-------------------------------------------------------------------*# |
---|
140 | Model trayReactTeste |
---|
141 | ATTRIBUTES |
---|
142 | Pallete = false; |
---|
143 | Icon = "icon/Tray"; |
---|
144 | Brief = "Model of a tray with reaction."; |
---|
145 | Info = |
---|
146 | "== Assumptions == |
---|
147 | * both phases (liquid and vapour) exists all the time; |
---|
148 | * thermodymanic equilibrium with Murphree plate efficiency; |
---|
149 | * no entrainment of liquid or vapour phase; |
---|
150 | * no weeping; |
---|
151 | * the dymanics in the downcomer are neglected. |
---|
152 | |
---|
153 | == Specify == |
---|
154 | * the Feed stream; |
---|
155 | * the Liquid inlet stream; |
---|
156 | * the Vapour inlet stream; |
---|
157 | * the Vapour outlet flow (OutletV.F); |
---|
158 | * the reaction related variables. |
---|
159 | |
---|
160 | == Initial == |
---|
161 | * the plate temperature (OutletL.T) |
---|
162 | * the liquid height (Level) OR the liquid flow OutletL.F |
---|
163 | * (NoComps - 1) OutletL compositions |
---|
164 | "; |
---|
165 | |
---|
166 | PARAMETERS |
---|
167 | outer PP as Plugin(Type="PP"); |
---|
168 | outer NComp as Integer; |
---|
169 | V as volume(Brief="Total Volume of the tray"); |
---|
170 | Q as power (Brief="Rate of heat supply"); |
---|
171 | Ap as area (Brief="Plate area = Atray - Adowncomer"); |
---|
172 | |
---|
173 | Ah as area (Brief="Total holes area"); |
---|
174 | lw as length (Brief="Weir length"); |
---|
175 | g as acceleration (Default=9.81); |
---|
176 | hw as length (Brief="Weir height"); |
---|
177 | beta as fraction (Brief="Aeration fraction"); |
---|
178 | alfa as fraction (Brief="Dry pressure drop coefficient"); |
---|
179 | |
---|
180 | stoic(NComp) as Real(Brief="Stoichiometric matrix"); |
---|
181 | Hr as energy_mol; |
---|
182 | Pstartup as pressure; |
---|
183 | |
---|
184 | VapourFlow as Switcher(Valid = ["on", "off"], Default = "off"); |
---|
185 | LiquidFlow as Switcher(Valid = ["on", "off"], Default = "off"); |
---|
186 | |
---|
187 | VARIABLES |
---|
188 | in Inlet as stream (Brief="Feed stream", PosX=0, PosY=0.4932, Symbol="_{in}"); |
---|
189 | in InletL as stream (Brief="Inlet liquid stream", PosX=0.5195, PosY=0, Symbol="_{inL}"); |
---|
190 | in InletV as stream (Brief="Inlet vapour stream", PosX=0.4994, PosY=1, Symbol="_{inV}"); |
---|
191 | out OutletL as liquid_stream (Brief="Outlet liquid stream", PosX=0.8277, PosY=1, Symbol="_{outL}"); |
---|
192 | out OutletV as vapour_stream (Brief="Outlet vapour stream", PosX=0.8043, PosY=0, Symbol="_{outV}"); |
---|
193 | |
---|
194 | yideal(NComp) as fraction; |
---|
195 | Emv as Real (Brief = "Murphree efficiency"); |
---|
196 | |
---|
197 | M(NComp) as mol (Brief="Molar Holdup in the tray"); |
---|
198 | ML as mol (Brief="Molar liquid holdup"); |
---|
199 | MV as mol (Brief="Molar vapour holdup"); |
---|
200 | E as energy (Brief="Total Energy Holdup on tray"); |
---|
201 | vL as volume_mol (Brief="Liquid Molar Volume"); |
---|
202 | vV as volume_mol (Brief="Vapour Molar volume"); |
---|
203 | Level as length (Brief="Height of clear liquid on plate"); |
---|
204 | Vol as volume; |
---|
205 | |
---|
206 | rhoL as dens_mass; |
---|
207 | rhoV as dens_mass; |
---|
208 | r3 as reaction_mol (Brief = "Reaction resulting ethyl acetate", DisplayUnit = 'mol/l/s'); |
---|
209 | C(NComp) as conc_mol (Brief = "Molar concentration", Lower = -1); #, Unit = "mol/l"); |
---|
210 | |
---|
211 | EQUATIONS |
---|
212 | "Molar Concentration" |
---|
213 | OutletL.z = vL * C; |
---|
214 | |
---|
215 | "Reaction" |
---|
216 | r3 = exp(-7150*'K'/OutletL.T)*(4.85e4*C(1)*C(2) - 1.23e4*C(3)*C(4))*'l/mol/s'; |
---|
217 | |
---|
218 | "Component Molar Balance" |
---|
219 | diff(M)=Inlet.F*Inlet.z + InletL.F*InletL.z + InletV.F*InletV.z |
---|
220 | - OutletL.F*OutletL.z - OutletV.F*OutletV.z + stoic*r3*ML*vL; |
---|
221 | |
---|
222 | "Energy Balance" |
---|
223 | diff(E) = ( Inlet.F*Inlet.h + InletL.F*InletL.h + InletV.F*InletV.h |
---|
224 | - OutletL.F*OutletL.h - OutletV.F*OutletV.h + Q ) + Hr * r3 * vL*ML; |
---|
225 | |
---|
226 | "Molar Holdup" |
---|
227 | M = ML*OutletL.z + MV*OutletV.z; |
---|
228 | |
---|
229 | "Energy Holdup" |
---|
230 | E = ML*OutletL.h + MV*OutletV.h - OutletL.P*V; |
---|
231 | |
---|
232 | "Mol fraction normalisation" |
---|
233 | sum(OutletL.z)= 1.0; |
---|
234 | |
---|
235 | "Liquid Volume" |
---|
236 | vL = PP.LiquidVolume(OutletL.T, OutletL.P, OutletL.z); |
---|
237 | "Vapour Volume" |
---|
238 | vV = PP.VapourVolume(OutletV.T, OutletV.P, OutletV.z); |
---|
239 | |
---|
240 | "Thermal Equilibrium" |
---|
241 | OutletV.T = OutletL.T; |
---|
242 | |
---|
243 | "Mechanical Equilibrium" |
---|
244 | OutletV.P = OutletL.P; |
---|
245 | |
---|
246 | "Level of clear liquid over the weir" |
---|
247 | Level = ML*vL/Ap; |
---|
248 | |
---|
249 | Vol = ML*vL; |
---|
250 | |
---|
251 | "Liquid Density" |
---|
252 | rhoL = PP.LiquidDensity(OutletL.T, OutletL.P, OutletL.z); |
---|
253 | "Vapour Density" |
---|
254 | rhoV = PP.VapourDensity(InletV.T, InletV.P, InletV.z); |
---|
255 | |
---|
256 | switch LiquidFlow |
---|
257 | case "on": |
---|
258 | "Francis Equation" |
---|
259 | OutletL.F*vL = 1.84*'1/s'*lw*((Level-(beta*hw)+1e-6*'m')/(beta))^2; |
---|
260 | when Level < (beta * hw) switchto "off"; |
---|
261 | |
---|
262 | case "off": |
---|
263 | "Low level" |
---|
264 | OutletL.F = 0 * 'mol/h'; |
---|
265 | when Level > (beta * hw) + 1e-6*'m' switchto "on"; |
---|
266 | end |
---|
267 | |
---|
268 | switch VapourFlow |
---|
269 | case "on": |
---|
270 | #InletV.P = OutletV.P + Level*g*rhoL + rhoV*alfa*(InletV.F*vV/Ah)^2; |
---|
271 | InletV.F*vV = sqrt((InletV.P - OutletV.P - Level*g*rhoL + 1e-8 * 'atm')/(rhoV*alfa))*Ah; |
---|
272 | when InletV.P < OutletV.P + Level*g*rhoL switchto "off"; |
---|
273 | |
---|
274 | case "off": |
---|
275 | InletV.F = 0 * 'mol/s'; |
---|
276 | when InletV.P > OutletV.P + Level*g*rhoL + 3e-2 * 'atm' switchto "on"; |
---|
277 | #when InletV.P > OutletV.P + Level*beta*g*rhoL + 1e-2 * 'atm' switchto "on"; |
---|
278 | end |
---|
279 | |
---|
280 | "Chemical Equilibrium" |
---|
281 | PP.LiquidFugacityCoefficient(OutletL.T, OutletL.P, OutletL.z)*OutletL.z = |
---|
282 | PP.VapourFugacityCoefficient(OutletV.T, OutletV.P, yideal)*yideal; |
---|
283 | |
---|
284 | OutletV.z = Emv * (yideal - InletV.z) + InletV.z; |
---|
285 | |
---|
286 | sum(OutletL.z)= sum(OutletV.z); |
---|
287 | |
---|
288 | "Geometry Constraint" |
---|
289 | V = ML* vL + MV*vV; |
---|
290 | end |
---|
291 | |
---|
292 | #*------------------------------------- |
---|
293 | * Model of a packed column stage |
---|
294 | -------------------------------------*# |
---|
295 | Model packedStageTeste |
---|
296 | ATTRIBUTES |
---|
297 | Pallete = false; |
---|
298 | Icon = "icon/PackedStage"; |
---|
299 | Brief = "Complete model of a packed column stage."; |
---|
300 | Info = |
---|
301 | "== Specify == |
---|
302 | * the Feed stream |
---|
303 | * the Liquid inlet stream |
---|
304 | * the Vapour inlet stream |
---|
305 | * the stage pressure drop (deltaP) |
---|
306 | |
---|
307 | == Initial == |
---|
308 | * the plate temperature (OutletL.T) |
---|
309 | * the liquid molar holdup ML |
---|
310 | * (NoComps - 1) OutletL compositions |
---|
311 | "; |
---|
312 | |
---|
313 | PARAMETERS |
---|
314 | outer PP as Plugin(Brief = "External Physical Properties", Type="PP"); |
---|
315 | outer NComp as Integer; |
---|
316 | PPwater as Plugin(Brief="Physical Properties", |
---|
317 | Type="PP", |
---|
318 | Components = [ "water" ], |
---|
319 | LiquidModel = "PR", |
---|
320 | VapourModel = "PR" |
---|
321 | ); |
---|
322 | |
---|
323 | V as volume(Brief="Total Volume of the tray"); |
---|
324 | Q as heat_rate (Brief="Rate of heat supply"); |
---|
325 | d as length (Brief="Column diameter"); |
---|
326 | |
---|
327 | a as Real (Brief="surface area per packing volume", Unit='m^2/m^3'); |
---|
328 | g as acceleration; |
---|
329 | e as Real (Brief="Void fraction of packing, m^3/m^3"); |
---|
330 | Cpo as Real (Brief="Constant for resitance equation"); # Billet and Schultes, 1999. |
---|
331 | Mw(NComp) as molweight (Brief = "Component Mol Weight"); |
---|
332 | hs as length (Brief="Height of the packing stage"); |
---|
333 | Qsil as positive (Brief="Resistance coefficient on the liquid load", Default=1); |
---|
334 | |
---|
335 | VARIABLES |
---|
336 | in Inlet as stream (Brief="Feed stream", PosX=0, PosY=0.4932, Symbol="_{in}"); |
---|
337 | in InletL as stream (Brief="Inlet liquid stream", PosX=0.5195, PosY=0, Symbol="_{inL}"); |
---|
338 | in InletV as stream (Brief="Inlet vapour stream", PosX=0.4994, PosY=1, Symbol="_{inV}"); |
---|
339 | out OutletL as liquid_stream (Brief="Outlet liquid stream", PosX=0.8277, PosY=1, Symbol="_{outL}"); |
---|
340 | out OutletV as vapour_stream (Brief="Outlet vapour stream", PosX=0.8043, PosY=0, Symbol="_{outV}"); |
---|
341 | |
---|
342 | M(NComp) as mol (Brief="Molar Holdup in the tray", Default=0.01, Lower=0, Upper=100); |
---|
343 | ML as mol (Brief="Molar liquid holdup", Default=0.01, Lower=0, Upper=100); |
---|
344 | MV as mol (Brief="Molar vapour holdup", Default=0.01, Lower=0, Upper=100); |
---|
345 | E as energy (Brief="Total Energy Holdup on tray", Default=-500); |
---|
346 | vL as volume_mol (Brief="Liquid Molar Volume"); |
---|
347 | vV as volume_mol (Brief="Vapour Molar volume"); |
---|
348 | |
---|
349 | miL as viscosity (Brief="Liquid dynamic viscosity", DisplayUnit='kg/m/s'); |
---|
350 | miV as viscosity (Brief="Vapor dynamic viscosity", DisplayUnit='kg/m/s'); |
---|
351 | rhoL as dens_mass; |
---|
352 | rhoV as dens_mass; |
---|
353 | |
---|
354 | deltaP as pressure; |
---|
355 | |
---|
356 | uL as velocity (Brief="volume flow rate of liquid, m^3/m^2/s", Lower=-10, Upper=100); |
---|
357 | uV as velocity (Brief="volume flow rate of vapor, m^3/m^2/s", Lower=-10, Upper=100); |
---|
358 | dp as length (Brief="Particle diameter", Default=1e-3, Lower=0, Upper=10); |
---|
359 | invK as positive (Brief="Wall factor", Default=1, Upper=10); |
---|
360 | Rev as Real (Brief="Reynolds number of the vapor stream", Default=4000); |
---|
361 | Al as area (Brief="Area occupied by the liquid", Default=0.001, Upper=1); |
---|
362 | hl as positive (Brief="Column holdup", Unit='m^3/m^3', Default=0.01,Upper=10); |
---|
363 | |
---|
364 | SET |
---|
365 | Mw = PP.MolecularWeight(); |
---|
366 | |
---|
367 | EQUATIONS |
---|
368 | "Component Molar Balance" |
---|
369 | diff(M)=Inlet.F*Inlet.z + InletL.F*InletL.z + InletV.F*InletV.z |
---|
370 | - OutletL.F*OutletL.z - OutletV.F*OutletV.z; |
---|
371 | |
---|
372 | "Energy Balance" |
---|
373 | diff(E) = ( Inlet.F*Inlet.h + InletL.F*InletL.h + InletV.F*InletV.h |
---|
374 | - OutletL.F*OutletL.h - OutletV.F*OutletV.h + Q ); |
---|
375 | |
---|
376 | "Molar Holdup" |
---|
377 | M = ML*OutletL.z + MV*OutletV.z; |
---|
378 | |
---|
379 | "Energy Holdup" |
---|
380 | E = ML*OutletL.h + MV*OutletV.h - OutletL.P*V; |
---|
381 | |
---|
382 | "Mol fraction normalisation" |
---|
383 | sum(OutletL.z)= 1.0; |
---|
384 | |
---|
385 | "Liquid Volume" |
---|
386 | vL = PP.LiquidVolume(OutletL.T, OutletL.P, OutletL.z); |
---|
387 | "Vapour Volume" |
---|
388 | vV = PP.VapourVolume(OutletV.T, OutletV.P, OutletV.z); |
---|
389 | |
---|
390 | "Chemical Equilibrium" |
---|
391 | PP.LiquidFugacityCoefficient(OutletL.T, OutletL.P, OutletL.z)*OutletL.z = |
---|
392 | PP.VapourFugacityCoefficient(OutletV.T, OutletV.P, OutletV.z)*OutletV.z; |
---|
393 | |
---|
394 | "Thermal Equilibrium" |
---|
395 | OutletV.T = OutletL.T; |
---|
396 | |
---|
397 | "Mechanical Equilibrium" |
---|
398 | OutletL.P = OutletV.P; |
---|
399 | |
---|
400 | "Geometry Constraint" |
---|
401 | V*e = ML*vL + MV*vV; |
---|
402 | |
---|
403 | "Liquid Density" |
---|
404 | rhoL = PP.LiquidDensity(OutletL.T, OutletL.P, OutletL.z); |
---|
405 | "Vapour Density" |
---|
406 | rhoV = PP.VapourDensity(InletV.T, InletV.P, InletV.z); |
---|
407 | "Liquid viscosity" |
---|
408 | miL = PP.LiquidViscosity(OutletL.T, OutletL.P, OutletL.z); |
---|
409 | "Vapour viscosity" |
---|
410 | miV = PP.VapourViscosity(InletV.T, InletV.P, InletV.z); |
---|
411 | |
---|
412 | "Area occupied by the liquid" |
---|
413 | Al = ML*vL/hs; |
---|
414 | |
---|
415 | "Volume flow rate of liquid, m^3/m^2/s" |
---|
416 | uL * Al = OutletL.F * vL; |
---|
417 | "Volume flow rate of vapor, m^3/m^2/s" |
---|
418 | uV * ((d^2*3.14159/4)*e - Al) = OutletV.F * vV; |
---|
419 | |
---|
420 | "Liquid holdup" |
---|
421 | hl = ML*vL/V/e; |
---|
422 | |
---|
423 | "Particle diameter" |
---|
424 | dp = 6 * (1-e)/a; |
---|
425 | |
---|
426 | "Wall Factor" |
---|
427 | invK = (1 + (2*dp/(3*d*(1-e)))); |
---|
428 | |
---|
429 | "Reynolds number of the vapor stream" |
---|
430 | Rev*invK = dp*uV*rhoV / (miV*(1-e)); |
---|
431 | |
---|
432 | deltaP = InletV.P - OutletV.P; |
---|
433 | |
---|
434 | "Pressure drop and Vapor flow" |
---|
435 | deltaP/hs = Qsil*a*uV^2*rhoV*invK / (2*(e-hl)^3); |
---|
436 | |
---|
437 | "Liquid holdup" |
---|
438 | hl = (12*miL*a^2*uL/rhoL/g)^1/3; |
---|
439 | end |
---|
440 | |
---|
441 | #*------------------------------------- |
---|
442 | * Nonequilibrium Model |
---|
443 | -------------------------------------*# |
---|
444 | Model interfaceTeste |
---|
445 | |
---|
446 | ATTRIBUTES |
---|
447 | Pallete = false; |
---|
448 | Icon = "icon/Tray"; |
---|
449 | Brief = "Descrition of variables of the equilibrium interface."; |
---|
450 | Info = |
---|
451 | "This model contains only the variables of the equilibrium interface."; |
---|
452 | |
---|
453 | PARAMETERS |
---|
454 | outer PP as Plugin(Brief = "External Physical Properties", Type="PP"); |
---|
455 | outer NComp as Integer; |
---|
456 | outer NC1 as Integer; |
---|
457 | |
---|
458 | VARIABLES |
---|
459 | NL(NComp) as flow_mol_delta (Brief = "Stream Molar Rate on Liquid Phase"); |
---|
460 | NV(NComp) as flow_mol_delta (Brief = "Stream Molar Rate on Vapour Phase"); |
---|
461 | T as temperature (Brief = "Stream Temperature"); |
---|
462 | P as pressure (Brief = "Stream Pressure"); |
---|
463 | x(NComp) as fraction (Brief = "Stream Molar Fraction on Liquid Phase"); |
---|
464 | y(NComp) as fraction (Brief = "Stream Molar Fraction on Vapour Phase"); |
---|
465 | a as area (Brief = "Interface Area"); |
---|
466 | htL as heat_trans_coeff (Brief = "Heat Transference Coefficient on Liquid Phase"); |
---|
467 | htV as heat_trans_coeff (Brief = "Heat Transference Coefficient on Vapour Phase"); |
---|
468 | E_liq as heat_rate (Brief = "Liquid Energy Rate at interface"); |
---|
469 | E_vap as heat_rate (Brief = "Vapour Energy Rate at interface"); |
---|
470 | hL as enth_mol (Brief = "Liquid Molar Enthalpy"); |
---|
471 | hV as enth_mol (Brief = "Vapour Molar Enthalpy"); |
---|
472 | kL(NC1,NC1) as velocity (Brief = "Mass Transfer Coefficients"); |
---|
473 | kV(NC1,NC1) as velocity (Brief = "Mass Transfer Coefficients"); |
---|
474 | |
---|
475 | EQUATIONS |
---|
476 | "Liquid Enthalpy" |
---|
477 | hL = PP.LiquidEnthalpy(T, P, x); |
---|
478 | |
---|
479 | "Vapour Enthalpy" |
---|
480 | hV = PP.VapourEnthalpy(T, P, y); |
---|
481 | |
---|
482 | end |
---|
483 | |
---|
484 | Model trayRateBasicTeste |
---|
485 | ATTRIBUTES |
---|
486 | Pallete = false; |
---|
487 | Icon = "icon/Tray"; |
---|
488 | Brief = "Basic equations of a tray rate column model."; |
---|
489 | Info = |
---|
490 | "This model contains only the main equations of a column tray nonequilibrium model without |
---|
491 | the hidraulic equations. |
---|
492 | |
---|
493 | == Assumptions == |
---|
494 | * both phases (liquid and vapour) exists all the time; |
---|
495 | * no entrainment of liquid or vapour phase; |
---|
496 | * no weeping; |
---|
497 | * the dymanics in the downcomer are neglected. |
---|
498 | "; |
---|
499 | |
---|
500 | PARAMETERS |
---|
501 | outer PP as Plugin(Brief = "External Physical Properties", Type="PP"); |
---|
502 | outer NComp as Integer; |
---|
503 | NC1 as Integer; |
---|
504 | V as volume(Brief="Total Volume of the tray"); |
---|
505 | Q as heat_rate (Brief="Rate of heat supply"); |
---|
506 | Ap as area (Brief="Plate area = Atray - Adowncomer"); |
---|
507 | |
---|
508 | VARIABLES |
---|
509 | in Inlet as stream (Brief="Feed stream", PosX=0, PosY=0.4932, Symbol="_{in}"); |
---|
510 | in InletFV as stream (Brief="Feed stream", PosX=0, PosY=0.4932, Symbol="_{in}"); |
---|
511 | in InletL as stream (Brief="Inlet liquid stream", PosX=0.5195, PosY=0, Symbol="_{inL}"); |
---|
512 | in InletV as stream (Brief="Inlet vapour stream", PosX=0.4994, PosY=1, Symbol="_{inV}"); |
---|
513 | out OutletL as liquid_stream (Brief="Outlet liquid stream", PosX=0.8277, PosY=1, Symbol="_{outL}"); |
---|
514 | out OutletV as vapour_stream (Brief="Outlet vapour stream", PosX=0.8043, PosY=0, Symbol="_{outV}"); |
---|
515 | |
---|
516 | M_liq(NComp) as mol (Brief="Liquid Molar Holdup in the tray"); |
---|
517 | M_vap(NComp) as mol (Brief="Vapour Molar Holdup in the tray"); |
---|
518 | ML as mol (Brief="Molar liquid holdup"); |
---|
519 | MV as mol (Brief="Molar vapour holdup"); |
---|
520 | E_liq as energy (Brief="Total Liquid Energy Holdup on tray"); |
---|
521 | E_vap as energy (Brief="Total Vapour Energy Holdup on tray"); |
---|
522 | vL as volume_mol (Brief="Liquid Molar Volume"); |
---|
523 | vV as volume_mol (Brief="Vapour Molar volume"); |
---|
524 | Level as length (Brief="Height of clear liquid on plate"); |
---|
525 | interf as interfaceTeste; |
---|
526 | |
---|
527 | SET |
---|
528 | NC1=NComp-1; |
---|
529 | |
---|
530 | EQUATIONS |
---|
531 | "Component Molar Balance" |
---|
532 | diff(M_liq)=Inlet.F*Inlet.z + InletL.F*InletL.z |
---|
533 | - OutletL.F*OutletL.z + interf.NL; |
---|
534 | |
---|
535 | diff(M_vap)=InletFV.F*InletFV.z + InletV.F*InletV.z |
---|
536 | - OutletV.F*OutletV.z - interf.NV; |
---|
537 | |
---|
538 | "Energy Balance" |
---|
539 | diff(E_liq) = Inlet.F*Inlet.h + InletL.F*InletL.h |
---|
540 | - OutletL.F*OutletL.h + Q + interf.E_liq; |
---|
541 | |
---|
542 | diff(E_vap) = InletFV.F*InletFV.h + InletV.F*InletV.h |
---|
543 | - OutletV.F*OutletV.h - interf.E_vap; |
---|
544 | |
---|
545 | "Molar Holdup" |
---|
546 | M_liq = ML*OutletL.z; |
---|
547 | |
---|
548 | M_vap = MV*OutletV.z; |
---|
549 | |
---|
550 | "Energy Holdup" |
---|
551 | E_liq = ML*(OutletL.h - OutletL.P*vL); |
---|
552 | |
---|
553 | E_vap = MV*(OutletV.h - OutletV.P*vV); |
---|
554 | |
---|
555 | "Energy Rate through the interface" |
---|
556 | interf.E_liq = interf.htL*interf.a*(interf.T-OutletL.T)+sum(interf.NL)*interf.hL; |
---|
557 | |
---|
558 | interf.E_vap = interf.htV*interf.a*(OutletV.T-interf.T)+sum(interf.NV)*interf.hV; |
---|
559 | |
---|
560 | "Mass Conservation" |
---|
561 | interf.NL = interf.NV; |
---|
562 | |
---|
563 | "Energy Conservation" |
---|
564 | interf.E_liq = interf.E_vap; |
---|
565 | |
---|
566 | "Mol fraction normalisation" |
---|
567 | sum(OutletL.z)= 1.0; |
---|
568 | sum(OutletL.z)= sum(OutletV.z); |
---|
569 | sum(interf.x)=1.0; |
---|
570 | sum(interf.x)=sum(interf.y); |
---|
571 | |
---|
572 | "Liquid Volume" |
---|
573 | vL = PP.LiquidVolume(OutletL.T, OutletL.P, OutletL.z); |
---|
574 | "Vapour Volume" |
---|
575 | vV = PP.VapourVolume(OutletV.T, OutletV.P, OutletV.z); |
---|
576 | |
---|
577 | "Chemical Equilibrium" |
---|
578 | PP.LiquidFugacityCoefficient(interf.T, interf.P, interf.x)*interf.x = |
---|
579 | PP.VapourFugacityCoefficient(interf.T, interf.P, interf.y)*interf.y; |
---|
580 | |
---|
581 | "Geometry Constraint" |
---|
582 | V = ML*vL + MV*vV; |
---|
583 | |
---|
584 | "Level of clear liquid over the weir" |
---|
585 | Level = ML*vL/Ap; |
---|
586 | |
---|
587 | "Total Mass Transfer Rates" |
---|
588 | interf.NL(1:NC1)=interf.a*sumt(interf.kL*(interf.x(1:NC1)-OutletL.z(1:NC1)))/vL+ |
---|
589 | OutletL.z(1:NC1)*sum(interf.NL); |
---|
590 | |
---|
591 | # interf.NL(1:NC1)=0.01*'kmol/s'; |
---|
592 | |
---|
593 | interf.NV(1:NC1)=interf.a*sumt(interf.kV*(OutletV.z(1:NC1)-interf.y(1:NC1)))/vV+ |
---|
594 | OutletV.z(1:NC1)*sum(interf.NV); |
---|
595 | |
---|
596 | "Mechanical Equilibrium" |
---|
597 | OutletV.P = OutletL.P; |
---|
598 | interf.P=OutletL.P; |
---|
599 | end |
---|
600 | |
---|
601 | Model trayRateTeste as trayRateBasicTeste |
---|
602 | ATTRIBUTES |
---|
603 | Pallete = false; |
---|
604 | Icon = "icon/Tray"; |
---|
605 | Brief = "Complete rate model of a column tray."; |
---|
606 | Info = |
---|
607 | "== Specify == |
---|
608 | * the Feed stream |
---|
609 | * the Liquid inlet stream |
---|
610 | * the Vapour inlet stream |
---|
611 | * the Vapour outlet flow (OutletV.F) |
---|
612 | |
---|
613 | == Initial == |
---|
614 | * the plate temperature of both phases (OutletL.T and OutletV.T) |
---|
615 | * the liquid height (Level) OR the liquid flow holdup (ML) |
---|
616 | * the vapor holdup (MV) |
---|
617 | * (NoComps - 1) OutletL compositions |
---|
618 | "; |
---|
619 | |
---|
620 | PARAMETERS |
---|
621 | Ah as area (Brief="Total holes area"); |
---|
622 | lw as length (Brief="Weir length"); |
---|
623 | g as acceleration (Default=9.81); |
---|
624 | hw as length (Brief="Weir height"); |
---|
625 | beta as fraction (Brief="Aeration fraction"); |
---|
626 | alfa as fraction (Brief="Dry pressure drop coefficient"); |
---|
627 | |
---|
628 | VapourFlow as Switcher(Valid = ["on", "off"], Default = "on"); |
---|
629 | LiquidFlow as Switcher(Valid = ["on", "off"], Default = "on"); |
---|
630 | |
---|
631 | VARIABLES |
---|
632 | rhoL as dens_mass; |
---|
633 | rhoV as dens_mass; |
---|
634 | |
---|
635 | EQUATIONS |
---|
636 | "Liquid Density" |
---|
637 | rhoL = PP.LiquidDensity(OutletL.T, OutletL.P, OutletL.z); |
---|
638 | "Vapour Density" |
---|
639 | rhoV = PP.VapourDensity(InletV.T, InletV.P, InletV.z); |
---|
640 | |
---|
641 | switch LiquidFlow |
---|
642 | case "on": |
---|
643 | "Francis Equation" |
---|
644 | # OutletL.F*vL = 1.84*'m^0.5/s'*lw*((Level-(beta*hw))/(beta))^1.5; |
---|
645 | OutletL.F*vL = 1.84*'1/s'*lw*((Level-(beta*hw))/(beta))^2; |
---|
646 | when Level < (beta * hw) switchto "off"; |
---|
647 | |
---|
648 | case "off": |
---|
649 | "Low level" |
---|
650 | OutletL.F = 0 * 'mol/h'; |
---|
651 | when Level > (beta * hw) + 1e-6*'m' switchto "on"; |
---|
652 | end |
---|
653 | |
---|
654 | switch VapourFlow |
---|
655 | case "on": |
---|
656 | InletV.F*vV = sqrt((InletV.P - OutletV.P)/(rhoV*alfa))*Ah; |
---|
657 | when InletV.F < 1e-6 * 'kmol/h' switchto "off"; |
---|
658 | |
---|
659 | case "off": |
---|
660 | InletV.F = 0 * 'mol/s'; |
---|
661 | when InletV.P > OutletV.P + Level*g*rhoL + 1e-1 * 'atm' switchto "on"; |
---|
662 | end |
---|
663 | end |
---|