1 | #*------------------------------------------------------------------- |
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2 | * EMSO Model Library (EML) Copyright (C) 2004 - 2007 ALSOC. |
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3 | * |
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4 | * This LIBRARY is free software; you can distribute it and/or modify |
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5 | * it under the therms of the ALSOC FREE LICENSE as available at |
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6 | * http://www.enq.ufrgs.br/alsoc. |
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7 | * |
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8 | * EMSO Copyright (C) 2004 - 2007 ALSOC, original code |
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9 | * from http://www.rps.eng.br Copyright (C) 2002-2004. |
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10 | * All rights reserved. |
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11 | * |
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12 | * EMSO is distributed under the therms of the ALSOC LICENSE as |
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13 | * available at http://www.enq.ufrgs.br/alsoc. |
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14 | * |
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15 | *---------------------------------------------------------------------- |
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16 | * Author: Paula B. Staudt |
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17 | * $Id: tray.mso 522 2008-05-21 23:21:12Z arge $ |
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18 | *--------------------------------------------------------------------*# |
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19 | |
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20 | using "streams"; |
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21 | |
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22 | Model trayBasic |
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23 | ATTRIBUTES |
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24 | Pallete = false; |
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25 | Icon = "icon/Tray"; |
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26 | Brief = "Basic equations of a tray column model."; |
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27 | Info = |
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28 | "This model contains only the main equations of a column tray equilibrium model without |
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29 | the hidraulic equations. |
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30 | |
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31 | == Assumptions == |
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32 | * both phases (liquid and vapour) exists all the time; |
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33 | * thermodymanic equilibrium with Murphree plate efficiency; |
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34 | * no entrainment of liquid or vapour phase; |
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35 | * no weeping; |
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36 | * the dymanics in the downcomer are neglected. |
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37 | "; |
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38 | |
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39 | PARAMETERS |
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40 | outer PP as Plugin (Brief = "External Physical Properties", Type="PP"); |
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41 | outer NComp as Integer; |
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42 | |
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43 | VARIABLES |
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44 | |
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45 | Inlet as stream (Brief="Feed stream", Hidden=true, PosX=0, PosY=0.4932, Symbol="_{in}"); |
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46 | LiquidSideStream as liquid_stream (Brief="liquid Sidestream", Hidden=true, Symbol="_{outL}"); |
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47 | VapourSideStream as vapour_stream (Brief="vapour Sidestream", Hidden=true, Symbol="_{outV}"); |
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48 | |
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49 | in InletLiquid as stream (Brief="Inlet liquid stream", PosX=0.5195, PosY=0, Symbol="_{inL}"); |
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50 | in InletVapour as stream (Brief="Inlet vapour stream", PosX=0.4994, PosY=1, Symbol="_{inV}"); |
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51 | out OutletLiquid as liquid_stream (Brief="Outlet liquid stream", PosX=0.8277, PosY=1, Symbol="_{outL}"); |
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52 | out OutletVapour as vapour_stream (Brief="Outlet vapour stream", PosX=0.8043, PosY=0, Symbol="_{outV}"); |
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53 | |
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54 | |
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55 | M(NComp) as mol (Brief="Molar Holdup in the tray"); |
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56 | ML as mol (Brief="Molar liquid holdup"); |
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57 | MV as mol (Brief="Molar vapour holdup"); |
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58 | E as energy (Brief="Total Energy Holdup on tray"); |
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59 | vL as volume_mol (Brief="Liquid Molar Volume"); |
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60 | vV as volume_mol (Brief="Vapour Molar volume"); |
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61 | Level as length (Brief="Height of clear liquid on plate"); |
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62 | yideal(NComp) as fraction; |
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63 | |
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64 | |
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65 | EQUATIONS |
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66 | "Component Molar Balance" |
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67 | diff(M)=Inlet.F*Inlet.z + InletLiquid.F*InletLiquid.z + InletVapour.F*InletVapour.z- OutletLiquid.F*OutletLiquid.z - OutletVapour.F*OutletVapour.z- |
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68 | LiquidSideStream.F*LiquidSideStream.z-VapourSideStream.F*VapourSideStream.z; |
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69 | |
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70 | "Molar Holdup" |
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71 | M = ML*OutletLiquid.z + MV*OutletVapour.z; |
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72 | |
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73 | "Mol fraction normalisation" |
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74 | sum(OutletLiquid.z)= 1.0; |
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75 | sum(OutletLiquid.z)= sum(OutletVapour.z); |
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76 | |
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77 | "Liquid Volume" |
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78 | vL = PP.LiquidVolume(OutletLiquid.T, OutletLiquid.P, OutletLiquid.z); |
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79 | |
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80 | "Vapour Volume" |
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81 | vV = PP.VapourVolume(OutletVapour.T, OutletVapour.P, OutletVapour.z); |
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82 | |
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83 | "Chemical Equilibrium" |
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84 | PP.LiquidFugacityCoefficient(OutletLiquid.T, OutletLiquid.P, OutletLiquid.z)*OutletLiquid.z = PP.VapourFugacityCoefficient(OutletVapour.T, OutletVapour.P, yideal)*yideal; |
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85 | |
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86 | "Thermal Equilibrium" |
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87 | OutletVapour.T = OutletLiquid.T; |
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88 | |
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89 | "Mechanical Equilibrium" |
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90 | OutletVapour.P = OutletLiquid.P; |
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91 | |
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92 | "Thermal Equilibrium Vapour Side Stream" |
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93 | OutletVapour.T = VapourSideStream.T; |
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94 | |
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95 | "Thermal Equilibrium Liquid Side Stream" |
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96 | OutletLiquid.T = LiquidSideStream.T; |
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97 | |
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98 | "Mechanical Equilibrium Vapour Side Stream" |
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99 | OutletVapour.P= VapourSideStream.P; |
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100 | |
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101 | "Mechanical Equilibrium Liquid Side Stream" |
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102 | OutletLiquid.P = LiquidSideStream.P; |
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103 | |
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104 | "Composition Liquid Side Stream" |
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105 | OutletLiquid.z= LiquidSideStream.z; |
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106 | |
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107 | "Composition Vapour Side Stream" |
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108 | OutletVapour.z= VapourSideStream.z; |
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109 | |
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110 | end |
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111 | |
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112 | Model tray as trayBasic |
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113 | ATTRIBUTES |
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114 | Pallete = false; |
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115 | Icon = "icon/Tray"; |
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116 | Brief = "Complete model of a column tray."; |
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117 | Info = |
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118 | "== Specify == |
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119 | * the Feed stream |
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120 | * the Liquid inlet stream |
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121 | * the Vapour inlet stream |
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122 | * the Vapour outlet flow (OutletVapour.F) |
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123 | |
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124 | == Initial == |
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125 | * the plate temperature (OutletLiquid.T) |
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126 | * the liquid height (Level) OR the liquid flow OutletLiquid.F |
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127 | * (NoComps - 1) OutletLiquid compositions |
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128 | |
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129 | == Options == |
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130 | You can choose the equation for the liquid outlet flow and the vapour |
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131 | inlet flow calculation through the VapourFlowModel and LiquidFlowModel |
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132 | switchers. |
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133 | |
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134 | == References == |
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135 | * ELGUE, S.; PRAT, L.; CABASSUD, M.; LANN, J. L.; CéZERAC, J. Dynamic models for start-up operations of batch distillation columns with experimental validation. Computers and Chemical Engineering, v. 28, p. 2735-2747, 2004. |
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136 | * FEEHERY, W. F. Dynamic Optimization with Path Constraints. Tese (Doutorado) - Massachusetts Institute of Technology, June 1998. |
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137 | * KLINGBERG, A. Modeling and Optimization of Batch Distillation. Dissertação (Mestrado) - Department of Automatic Control, Lund Institute of Technology, Lund, Sweden, fev. 2000. |
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138 | * OLSEN, I.; ENDRESTOL, G. O.; SIRA, T. A rigorous and efficient distillation column model for engineering and training simulators. Computers and Chemical Engineering,v. 21, n. Suppl, p. S193-S198, 1997. |
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139 | * REEPMEYER, F.; REPKE, J.-U.; WOZNY, G. Analysis of the start-up process for reactive distillation. Chemical Engineering Technology, v. 26, p. 81-86, 2003. |
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140 | * ROFFEL, B.; BETLEM, B.; RUIJTER, J. de. First principles dynamic modeling and multivariable control of a cryogenic distillation column process. Computers and Chemical Engineering, v. 24, p. 111-123, 2000. |
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141 | * WANG, L.; LI, P.; WOZNY, G.; WANG, S. A start-up model for simulation of batch distillation starting from a cold state. Computers and Chemical Engineering, v. 27, p.1485-1497, 2003. |
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142 | "; |
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143 | |
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144 | VARIABLES |
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145 | rhoL as dens_mass; |
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146 | rhoV as dens_mass; |
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147 | |
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148 | EQUATIONS |
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149 | |
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150 | "Liquid Density" |
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151 | rhoL = PP.LiquidDensity(OutletLiquid.T, OutletLiquid.P, OutletLiquid.z); |
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152 | |
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153 | "Vapour Density" |
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154 | rhoV = PP.VapourDensity(InletVapour.T, InletVapour.P, InletVapour.z); |
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155 | |
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156 | end |
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157 | |
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158 | #*------------------------------------------------------------------- |
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159 | * Model of a tray with reaction |
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160 | *-------------------------------------------------------------------*# |
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161 | Model trayReac |
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162 | ATTRIBUTES |
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163 | Pallete = false; |
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164 | Icon = "icon/Tray"; |
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165 | Brief = "Model of a tray with reaction."; |
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166 | Info = |
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167 | "== Assumptions == |
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168 | * both phases (liquid and vapour) exists all the time; |
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169 | * thermodymanic equilibrium with Murphree plate efficiency; |
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170 | * no entrainment of liquid or vapour phase; |
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171 | * no weeping; |
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172 | * the dymanics in the downcomer are neglected. |
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173 | |
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174 | == Specify == |
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175 | * the Feed stream; |
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176 | * the Liquid inlet stream; |
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177 | * the Vapour inlet stream; |
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178 | * the Vapour outlet flow (OutletVapour.F); |
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179 | * the reaction related variables. |
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180 | |
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181 | == Initial == |
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182 | * the plate temperature (OutletLiquid.T) |
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183 | * the liquid height (Level) OR the liquid flow OutletLiquid.F |
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184 | * (NoComps - 1) OutletLiquid compositions |
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185 | "; |
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186 | |
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187 | PARAMETERS |
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188 | |
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189 | outer PP as Plugin(Type="PP"); |
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190 | outer NComp as Integer; |
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191 | |
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192 | VARIABLES |
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193 | |
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194 | Inlet as stream (Brief="Feed stream", PosX=0, PosY=0.4932, Symbol="_{in}"); |
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195 | LiquidSideStream as liquid_stream (Brief="liquid Sidestream", Hidden=true, Symbol="_{outL}"); |
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196 | VapourSideStream as vapour_stream (Brief="vapour Sidestream", Hidden=true, Symbol="_{outV}"); |
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197 | |
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198 | |
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199 | in InletLiquid as stream (Brief="Inlet liquid stream", PosX=0.5195, PosY=0, Symbol="_{inL}"); |
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200 | in InletVapour as stream (Brief="Inlet vapour stream", PosX=0.4994, PosY=1, Symbol="_{inV}"); |
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201 | out OutletLiquid as liquid_stream (Brief="Outlet liquid stream", PosX=0.8277, PosY=1, Symbol="_{outL}"); |
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202 | out OutletVapour as vapour_stream (Brief="Outlet vapour stream", PosX=0.8043, PosY=0, Symbol="_{outV}"); |
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203 | |
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204 | yideal(NComp) as fraction; |
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205 | |
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206 | M(NComp) as mol (Brief="Molar Holdup in the tray"); |
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207 | ML as mol (Brief="Molar liquid holdup"); |
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208 | MV as mol (Brief="Molar vapour holdup"); |
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209 | E as energy (Brief="Total Energy Holdup on tray"); |
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210 | vL as volume_mol (Brief="Liquid Molar Volume"); |
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211 | vV as volume_mol (Brief="Vapour Molar volume"); |
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212 | Level as length (Brief="Height of clear liquid on plate"); |
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213 | Vol as volume; |
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214 | |
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215 | rhoL as dens_mass; |
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216 | rhoV as dens_mass; |
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217 | r3 as reaction_mol (Brief = "Reaction resulting ethyl acetate", DisplayUnit = 'mol/l/s'); |
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218 | C(NComp) as conc_mol (Brief = "Molar concentration", Lower = -1); |
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219 | |
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220 | EQUATIONS |
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221 | |
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222 | "Molar Concentration" |
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223 | OutletLiquid.z = vL * C; |
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224 | |
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225 | "Reaction" |
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226 | r3 = exp(-7150*'K'/OutletLiquid.T)*(4.85e4*C(1)*C(2) - 1.23e4*C(3)*C(4))*'l/mol/s'; |
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227 | |
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228 | "Molar Holdup" |
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229 | M = ML*OutletLiquid.z + MV*OutletVapour.z; |
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230 | |
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231 | "Thermal Equilibrium Vapour Side Stream" |
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232 | OutletVapour.T = VapourSideStream.T; |
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233 | |
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234 | "Thermal Equilibrium Liquid Side Stream" |
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235 | OutletLiquid.T = LiquidSideStream.T; |
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236 | |
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237 | "Mechanical Equilibrium Vapour Side Stream" |
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238 | OutletVapour.P= VapourSideStream.P; |
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239 | |
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240 | "Mechanical Equilibrium Liquid Side Stream" |
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241 | OutletLiquid.P = LiquidSideStream.P; |
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242 | |
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243 | "Composition Liquid Side Stream" |
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244 | OutletLiquid.z= LiquidSideStream.z; |
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245 | |
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246 | "Composition Vapour Side Stream" |
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247 | OutletVapour.z= VapourSideStream.z; |
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248 | |
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249 | "Mol fraction normalisation" |
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250 | sum(OutletLiquid.z)= 1.0; |
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251 | |
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252 | "Liquid Volume" |
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253 | vL = PP.LiquidVolume(OutletLiquid.T, OutletLiquid.P, OutletLiquid.z); |
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254 | |
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255 | "Vapour Volume" |
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256 | vV = PP.VapourVolume(OutletVapour.T, OutletVapour.P, OutletVapour.z); |
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257 | |
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258 | "Thermal Equilibrium" |
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259 | OutletVapour.T = OutletLiquid.T; |
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260 | |
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261 | "Mechanical Equilibrium" |
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262 | OutletVapour.P = OutletLiquid.P; |
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263 | |
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264 | Vol = ML*vL; |
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265 | |
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266 | "Liquid Density" |
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267 | rhoL = PP.LiquidDensity(OutletLiquid.T, OutletLiquid.P, OutletLiquid.z); |
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268 | |
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269 | "Vapour Density" |
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270 | rhoV = PP.VapourDensity(InletVapour.T, InletVapour.P, InletVapour.z); |
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271 | |
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272 | "Chemical Equilibrium" |
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273 | PP.LiquidFugacityCoefficient(OutletLiquid.T, OutletLiquid.P, OutletLiquid.z)*OutletLiquid.z = PP.VapourFugacityCoefficient(OutletVapour.T, OutletVapour.P, yideal)*yideal; |
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274 | |
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275 | sum(OutletLiquid.z)= sum(OutletVapour.z); |
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276 | |
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277 | end |
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278 | |
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279 | #*------------------------------------- |
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280 | * Model of a packed column stage |
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281 | -------------------------------------*# |
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282 | Model packedStage |
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283 | ATTRIBUTES |
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284 | Pallete = false; |
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285 | Icon = "icon/PackedStage"; |
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286 | Brief = "Complete model of a packed column stage."; |
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287 | Info = |
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288 | "== Specify == |
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289 | * the Feed stream |
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290 | * the Liquid inlet stream |
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291 | * the Vapour inlet stream |
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292 | * the stage pressure drop (deltaP) |
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293 | |
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294 | == Initial == |
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295 | * the plate temperature (OutletLiquid.T) |
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296 | * the liquid molar holdup ML |
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297 | * (NoComps - 1) OutletLiquid compositions |
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298 | "; |
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299 | |
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300 | PARAMETERS |
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301 | |
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302 | outer PP as Plugin(Brief = "External Physical Properties", Type="PP"); |
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303 | outer NComp as Integer; |
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304 | |
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305 | PPwater as Plugin(Brief="Physical Properties",Type="PP",Components = [ "water" ], |
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306 | LiquidModel = "PR", |
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307 | VapourModel = "PR" |
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308 | ); |
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309 | |
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310 | Mw(NComp) as molweight (Brief = "Component Mol Weight"); |
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311 | |
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312 | VARIABLES |
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313 | |
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314 | Inlet as stream (Brief="Feed stream", PosX=0, PosY=0.4932, Symbol="_{in}"); |
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315 | in InletLiquid as stream (Brief="Inlet liquid stream", PosX=0.5195, PosY=0, Symbol="_{inL}"); |
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316 | in InletVapour as stream (Brief="Inlet vapour stream", PosX=0.4994, PosY=1, Symbol="_{inV}"); |
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317 | out OutletLiquid as liquid_stream (Brief="Outlet liquid stream", PosX=0.8277, PosY=1, Symbol="_{outL}"); |
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318 | out OutletVapour as vapour_stream (Brief="Outlet vapour stream", PosX=0.8043, PosY=0, Symbol="_{outV}"); |
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319 | |
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320 | M(NComp) as mol (Brief="Molar Holdup in the tray", Default=0.01, Lower=0, Upper=100); |
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321 | ML as mol (Brief="Molar liquid holdup", Default=0.01, Lower=0, Upper=100); |
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322 | MV as mol (Brief="Molar vapour holdup", Default=0.01, Lower=0, Upper=100); |
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323 | E as energy (Brief="Total Energy Holdup on tray", Default=-500); |
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324 | vL as volume_mol (Brief="Liquid Molar Volume"); |
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325 | vV as volume_mol (Brief="Vapour Molar volume"); |
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326 | |
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327 | miL as viscosity (Brief="Liquid dynamic viscosity", DisplayUnit='kg/m/s'); |
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328 | miV as viscosity (Brief="Vapor dynamic viscosity", DisplayUnit='kg/m/s'); |
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329 | rhoL as dens_mass; |
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330 | rhoV as dens_mass; |
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331 | |
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332 | deltaP as pressure; |
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333 | |
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334 | uL as velocity (Brief="volume flow rate of liquid, m^3/m^2/s", Lower=-10, Upper=100); |
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335 | uV as velocity (Brief="volume flow rate of vapor, m^3/m^2/s", Lower=-10, Upper=100); |
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336 | dp as length (Brief="Particle diameter", Default=1e-3, Lower=0, Upper=10); |
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337 | invK as positive (Brief="Wall factor", Default=1, Upper=10); |
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338 | Rev as Real (Brief="Reynolds number of the vapor stream", Default=4000); |
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339 | Al as area (Brief="Area occupied by the liquid", Default=0.001, Upper=1); |
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340 | hl as positive (Brief="Column holdup", Unit='m^3/m^3', Default=0.01,Upper=10); |
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341 | |
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342 | SET |
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343 | Mw = PP.MolecularWeight(); |
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344 | |
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345 | EQUATIONS |
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346 | |
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347 | "Component Molar Balance" |
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348 | diff(M)=Inlet.F*Inlet.z + InletLiquid.F*InletLiquid.z + InletVapour.F*InletVapour.z- OutletLiquid.F*OutletLiquid.z - OutletVapour.F*OutletVapour.z; |
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349 | |
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350 | "Molar Holdup" |
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351 | M = ML*OutletLiquid.z + MV*OutletVapour.z; |
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352 | |
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353 | "Mol fraction normalisation" |
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354 | sum(OutletLiquid.z)= 1.0; |
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355 | |
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356 | "Liquid Volume" |
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357 | vL = PP.LiquidVolume(OutletLiquid.T, OutletLiquid.P, OutletLiquid.z); |
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358 | |
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359 | "Vapour Volume" |
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360 | vV = PP.VapourVolume(OutletVapour.T, OutletVapour.P, OutletVapour.z); |
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361 | |
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362 | "Chemical Equilibrium" |
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363 | PP.LiquidFugacityCoefficient(OutletLiquid.T, OutletLiquid.P, OutletLiquid.z)*OutletLiquid.z = PP.VapourFugacityCoefficient(OutletVapour.T, OutletVapour.P, OutletVapour.z)*OutletVapour.z; |
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364 | |
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365 | "Thermal Equilibrium" |
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366 | OutletVapour.T = OutletLiquid.T; |
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367 | |
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368 | "Mechanical Equilibrium" |
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369 | OutletLiquid.P = OutletVapour.P; |
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370 | |
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371 | "Liquid Density" |
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372 | rhoL = PP.LiquidDensity(OutletLiquid.T, OutletLiquid.P, OutletLiquid.z); |
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373 | |
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374 | "Vapour Density" |
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375 | rhoV = PP.VapourDensity(InletVapour.T, InletVapour.P, InletVapour.z); |
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376 | |
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377 | "Liquid viscosity" |
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378 | miL = PP.LiquidViscosity(OutletLiquid.T, OutletLiquid.P, OutletLiquid.z); |
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379 | |
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380 | "Vapour viscosity" |
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381 | miV = PP.VapourViscosity(InletVapour.T, InletVapour.P, InletVapour.z); |
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382 | |
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383 | "Volume flow rate of liquid, m^3/m^2/s" |
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384 | uL * Al = OutletLiquid.F * vL; |
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385 | |
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386 | deltaP = InletVapour.P - OutletVapour.P; |
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387 | |
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388 | end |
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389 | |
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390 | #*------------------------------------- |
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391 | * Nonequilibrium Model |
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392 | -------------------------------------* |
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393 | Model interfaceTeste |
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394 | |
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395 | ATTRIBUTES |
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396 | Pallete = false; |
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397 | Icon = "icon/Tray"; |
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398 | Brief = "Descrition of variables of the equilibrium interface."; |
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399 | Info = |
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400 | "This model contains only the variables of the equilibrium interface."; |
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401 | |
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402 | PARAMETERS |
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403 | outer PP as Plugin(Brief = "External Physical Properties", Type="PP"); |
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404 | outer NComp as Integer; |
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405 | outer NC1 as Integer; |
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406 | |
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407 | VARIABLES |
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408 | NL(NComp) as flow_mol_delta (Brief = "Stream Molar Rate on Liquid Phase"); |
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409 | NV(NComp) as flow_mol_delta (Brief = "Stream Molar Rate on Vapour Phase"); |
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410 | T as temperature (Brief = "Stream Temperature"); |
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411 | P as pressure (Brief = "Stream Pressure"); |
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412 | x(NComp) as fraction (Brief = "Stream Molar Fraction on Liquid Phase"); |
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413 | y(NComp) as fraction (Brief = "Stream Molar Fraction on Vapour Phase"); |
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414 | a as area (Brief = "Interface Area"); |
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415 | htL as heat_trans_coeff (Brief = "Heat Transference Coefficient on Liquid Phase"); |
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416 | htV as heat_trans_coeff (Brief = "Heat Transference Coefficient on Vapour Phase"); |
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417 | E_liq as heat_rate (Brief = "Liquid Energy Rate at interface"); |
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418 | E_vap as heat_rate (Brief = "Vapour Energy Rate at interface"); |
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419 | hL as enth_mol (Brief = "Liquid Molar Enthalpy"); |
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420 | hV as enth_mol (Brief = "Vapour Molar Enthalpy"); |
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421 | kL(NC1,NC1) as velocity (Brief = "Mass Transfer Coefficients"); |
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422 | kV(NC1,NC1) as velocity (Brief = "Mass Transfer Coefficients"); |
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423 | |
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424 | EQUATIONS |
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425 | "Liquid Enthalpy" |
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426 | hL = PP.LiquidEnthalpy(T, P, x); |
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427 | |
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428 | "Vapour Enthalpy" |
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429 | hV = PP.VapourEnthalpy(T, P, y); |
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430 | |
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431 | end |
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432 | |
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433 | Model trayRateBasicTeste |
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434 | ATTRIBUTES |
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435 | Pallete = false; |
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436 | Icon = "icon/Tray"; |
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437 | Brief = "Basic equations of a tray rate column model."; |
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438 | Info = |
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439 | "This model contains only the main equations of a column tray nonequilibrium model without |
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440 | the hidraulic equations. |
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441 | |
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442 | == Assumptions == |
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443 | * both phases (liquid and vapour) exists all the time; |
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444 | * no entrainment of liquid or vapour phase; |
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445 | * no weeping; |
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446 | * the dymanics in the downcomer are neglected. |
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447 | "; |
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448 | |
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449 | PARAMETERS |
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450 | outer PP as Plugin(Brief = "External Physical Properties", Type="PP"); |
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451 | outer NComp as Integer; |
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452 | NC1 as Integer; |
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453 | V as volume(Brief="Total Volume of the tray"); |
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454 | Q as heat_rate (Brief="Rate of heat supply"); |
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455 | Ap as area (Brief="Plate area = Atray - Adowncomer"); |
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456 | |
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457 | VARIABLES |
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458 | in Inlet as stream (Brief="Feed stream", PosX=0, PosY=0.4932, Symbol="_{in}"); |
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459 | in InletFV as stream (Brief="Feed stream", PosX=0, PosY=0.4932, Symbol="_{in}"); |
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460 | in InletLiquid as stream (Brief="Inlet liquid stream", PosX=0.5195, PosY=0, Symbol="_{inL}"); |
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461 | in InletVapour as stream (Brief="Inlet vapour stream", PosX=0.4994, PosY=1, Symbol="_{inV}"); |
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462 | out OutletLiquid as liquid_stream (Brief="Outlet liquid stream", PosX=0.8277, PosY=1, Symbol="_{outL}"); |
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463 | out OutletVapour as vapour_stream (Brief="Outlet vapour stream", PosX=0.8043, PosY=0, Symbol="_{outV}"); |
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464 | |
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465 | M_liq(NComp) as mol (Brief="Liquid Molar Holdup in the tray"); |
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466 | M_vap(NComp) as mol (Brief="Vapour Molar Holdup in the tray"); |
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467 | ML as mol (Brief="Molar liquid holdup"); |
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468 | MV as mol (Brief="Molar vapour holdup"); |
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469 | E_liq as energy (Brief="Total Liquid Energy Holdup on tray"); |
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470 | E_vap as energy (Brief="Total Vapour Energy Holdup on tray"); |
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471 | vL as volume_mol (Brief="Liquid Molar Volume"); |
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472 | vV as volume_mol (Brief="Vapour Molar volume"); |
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473 | Level as length (Brief="Height of clear liquid on plate"); |
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474 | interf as interfaceTeste; |
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475 | |
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476 | SET |
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477 | NC1=NComp-1; |
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478 | |
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479 | EQUATIONS |
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480 | "Component Molar Balance" |
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481 | diff(M_liq)=Inlet.F*Inlet.z + InletLiquid.F*InletLiquid.z |
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482 | - OutletLiquid.F*OutletLiquid.z + interf.NL; |
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483 | |
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484 | diff(M_vap)=InletFV.F*InletFV.z + InletVapour.F*InletVapour.z |
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485 | - OutletVapour.F*OutletVapour.z - interf.NV; |
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486 | |
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487 | "Energy Balance" |
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488 | diff(E_liq) = Inlet.F*Inlet.h + InletLiquid.F*InletLiquid.h |
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489 | - OutletLiquid.F*OutletLiquid.h + Q + interf.E_liq; |
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490 | |
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491 | diff(E_vap) = InletFV.F*InletFV.h + InletVapour.F*InletVapour.h |
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492 | - OutletVapour.F*OutletVapour.h - interf.E_vap; |
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493 | |
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494 | "Molar Holdup" |
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495 | M_liq = ML*OutletLiquid.z; |
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496 | |
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497 | M_vap = MV*OutletVapour.z; |
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498 | |
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499 | "Energy Holdup" |
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500 | E_liq = ML*(OutletLiquid.h - OutletLiquid.P*vL); |
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501 | |
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502 | E_vap = MV*(OutletVapour.h - OutletVapour.P*vV); |
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503 | |
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504 | "Energy Rate through the interface" |
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505 | interf.E_liq = interf.htL*interf.a*(interf.T-OutletLiquid.T)+sum(interf.NL)*interf.hL; |
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506 | |
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507 | interf.E_vap = interf.htV*interf.a*(OutletVapour.T-interf.T)+sum(interf.NV)*interf.hV; |
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508 | |
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509 | "Mass Conservation" |
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510 | interf.NL = interf.NV; |
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511 | |
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512 | "Energy Conservation" |
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513 | interf.E_liq = interf.E_vap; |
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514 | |
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515 | "Mol fraction normalisation" |
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516 | sum(OutletLiquid.z)= 1.0; |
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517 | sum(OutletLiquid.z)= sum(OutletVapour.z); |
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518 | sum(interf.x)=1.0; |
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519 | sum(interf.x)=sum(interf.y); |
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520 | |
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521 | "Liquid Volume" |
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522 | vL = PP.LiquidVolume(OutletLiquid.T, OutletLiquid.P, OutletLiquid.z); |
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523 | "Vapour Volume" |
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524 | vV = PP.VapourVolume(OutletVapour.T, OutletVapour.P, OutletVapour.z); |
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525 | |
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526 | "Chemical Equilibrium" |
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527 | PP.LiquidFugacityCoefficient(interf.T, interf.P, interf.x)*interf.x = |
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528 | PP.VapourFugacityCoefficient(interf.T, interf.P, interf.y)*interf.y; |
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529 | |
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530 | "Geometry Constraint" |
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531 | V = ML*vL + MV*vV; |
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532 | |
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533 | "Level of clear liquid over the weir" |
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534 | Level = ML*vL/Ap; |
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535 | |
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536 | "Total Mass Transfer Rates" |
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537 | interf.NL(1:NC1)=interf.a*sumt(interf.kL*(interf.x(1:NC1)-OutletLiquid.z(1:NC1)))/vL+ |
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538 | OutletLiquid.z(1:NC1)*sum(interf.NL); |
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539 | |
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540 | # interf.NL(1:NC1)=0.01*'kmol/s'; |
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541 | |
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542 | interf.NV(1:NC1)=interf.a*sumt(interf.kV*(OutletVapour.z(1:NC1)-interf.y(1:NC1)))/vV+ |
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543 | OutletVapour.z(1:NC1)*sum(interf.NV); |
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544 | |
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545 | "Mechanical Equilibrium" |
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546 | OutletVapour.P = OutletLiquid.P; |
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547 | interf.P=OutletLiquid.P; |
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548 | end |
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549 | |
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550 | Model trayRateTeste as trayRateBasicTeste |
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551 | ATTRIBUTES |
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552 | Pallete = false; |
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553 | Icon = "icon/Tray"; |
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554 | Brief = "Complete rate model of a column tray."; |
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555 | Info = |
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556 | "== Specify == |
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557 | * the Feed stream |
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558 | * the Liquid inlet stream |
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559 | * the Vapour inlet stream |
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560 | * the Vapour outlet flow (OutletVapour.F) |
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561 | |
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562 | == Initial == |
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563 | * the plate temperature of both phases (OutletLiquid.T and OutletVapour.T) |
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564 | * the liquid height (Level) OR the liquid flow holdup (ML) |
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565 | * the vapor holdup (MV) |
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566 | * (NoComps - 1) OutletLiquid compositions |
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567 | "; |
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568 | |
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569 | PARAMETERS |
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570 | Ah as area (Brief="Total holes area"); |
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571 | lw as length (Brief="Weir length"); |
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572 | g as acceleration (Default=9.81); |
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573 | hw as length (Brief="Weir height"); |
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574 | beta as fraction (Brief="Aeration fraction"); |
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575 | alfa as fraction (Brief="Dry pressure drop coefficient"); |
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576 | |
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577 | VapourFlow as Switcher(Valid = ["on", "off"], Default = "on"); |
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578 | LiquidFlow as Switcher(Valid = ["on", "off"], Default = "on"); |
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579 | |
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580 | VARIABLES |
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581 | rhoL as dens_mass; |
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582 | rhoV as dens_mass; |
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583 | |
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584 | EQUATIONS |
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585 | "Liquid Density" |
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586 | rhoL = PP.LiquidDensity(OutletLiquid.T, OutletLiquid.P, OutletLiquid.z); |
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587 | "Vapour Density" |
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588 | rhoV = PP.VapourDensity(InletVapour.T, InletVapour.P, InletVapour.z); |
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589 | |
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590 | switch LiquidFlow |
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591 | case "on": |
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592 | "Francis Equation" |
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593 | # OutletLiquid.F*vL = 1.84*'m^0.5/s'*lw*((Level-(beta*hw))/(beta))^1.5; |
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594 | OutletLiquid.F*vL = 1.84*'1/s'*lw*((Level-(beta*hw))/(beta))^2; |
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595 | when Level < (beta * hw) switchto "off"; |
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596 | |
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597 | case "off": |
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598 | "Low level" |
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599 | OutletLiquid.F = 0 * 'mol/h'; |
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600 | when Level > (beta * hw) + 1e-6*'m' switchto "on"; |
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601 | end |
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602 | |
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603 | switch VapourFlow |
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604 | case "on": |
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605 | InletVapour.F*vV = sqrt((InletVapour.P - OutletVapour.P)/(rhoV*alfa))*Ah; |
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606 | when InletVapour.F < 1e-6 * 'kmol/h' switchto "off"; |
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607 | |
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608 | case "off": |
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609 | InletVapour.F = 0 * 'mol/s'; |
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610 | when InletVapour.P > OutletVapour.P + Level*g*rhoL + 1e-1 * 'atm' switchto "on"; |
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611 | end |
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612 | end |
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613 | |
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614 | *# |
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