1 | #*------------------------------------------------------------------- |
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2 | * EMSO Model Library (EML) Copyright (C) 2004 - 2007 ALSOC. |
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3 | * |
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4 | * This LIBRARY is free software; you can distribute it and/or modify |
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5 | * it under the therms of the ALSOC FREE LICENSE as available at |
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6 | * http://www.enq.ufrgs.br/alsoc. |
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7 | * |
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8 | * EMSO Copyright (C) 2004 - 2007 ALSOC, original code |
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9 | * from http://www.rps.eng.br Copyright (C) 2002-2004. |
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10 | * All rights reserved. |
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11 | * |
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12 | * EMSO is distributed under the therms of the ALSOC LICENSE as |
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13 | * available at http://www.enq.ufrgs.br/alsoc. |
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14 | * |
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15 | *---------------------------------------------------------------------- |
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16 | * Author: Paula B. Staudt |
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17 | * $Id: reboiler.mso 555 2008-07-18 19:01:13Z rafael $ |
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18 | *--------------------------------------------------------------------*# |
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19 | |
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20 | using "streams"; |
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21 | |
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22 | Model reboiler2 |
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23 | ATTRIBUTES |
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24 | Pallete = true; |
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25 | Icon = "icon/Reboiler"; |
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26 | Brief = "Model of a dynamic reboiler - kettle."; |
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27 | Info = |
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28 | "== Assumptions == |
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29 | |
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30 | * perfect mixing of both phases; |
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31 | * thermodynamics equilibrium; |
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32 | * no liquid entrainment in the vapour stream. |
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33 | |
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34 | == Specify == |
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35 | |
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36 | * the inlet stream; |
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37 | * the liquid inlet stream; |
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38 | * the outlet flows: OutletVapour.F and OutletLiquid.F; |
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39 | * the heat supply. |
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40 | |
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41 | == Initial Conditions == |
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42 | |
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43 | * the reboiler temperature (OutletLiquid.T); |
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44 | * the reboiler liquid level (Level); |
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45 | * (NoComps - 1) OutletLiquid (OR OutletVapour) compositions. |
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46 | "; |
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47 | |
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48 | PARAMETERS |
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49 | outer PP as Plugin (Brief = "External Physical Properties", Type="PP"); |
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50 | outer NComp as Integer; |
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51 | Across as area (Brief="Cross Section Area of reboiler"); |
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52 | V as volume (Brief="Total volume of reboiler"); |
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53 | |
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54 | Initial_Level as length (Brief="Initial Level of liquid phase"); |
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55 | Initial_Temperature as temperature (Brief="Initial Temperature of Reboiler"); |
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56 | Initial_Composition(NComp) as fraction (Brief="Initial Liquid Composition"); |
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57 | |
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58 | VARIABLES |
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59 | |
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60 | in InletLiquid as stream (Brief="Liquid inlet stream", PosX=0.15, PosY=1, Symbol="_{inL}"); |
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61 | out OutletLiquid as liquid_stream (Brief="Liquid outlet stream", PosX=0.40, PosY=1, Symbol="_{outL}"); |
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62 | out OutletVapour as vapour_stream (Brief="Vapour outlet stream", PosX=0.40, PosY=0, Symbol="_{outV}"); |
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63 | in InletQ as power (Brief="Heat supplied", PosX=1, PosY=0, Symbol="_{in}"); |
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64 | |
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65 | M(NComp) as mol (Brief="Molar Holdup in the tray"); |
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66 | ML as mol (Brief="Molar liquid holdup"); |
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67 | MV as mol (Brief="Molar vapour holdup"); |
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68 | E as energy (Brief="Total Energy Holdup on tray"); |
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69 | vL as volume_mol (Brief="Liquid Molar Volume"); |
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70 | vV as volume_mol (Brief="Vapour Molar volume"); |
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71 | Level as length (Brief="Level of liquid phase"); |
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72 | rhoV as dens_mass (Brief="Vapour Density"); |
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73 | |
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74 | INITIAL |
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75 | |
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76 | Level = Initial_Level; |
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77 | OutletLiquid.T = Initial_Temperature; |
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78 | OutletLiquid.z(1:NComp-1) = Initial_Composition(1:NComp-1)/sum(Initial_Composition); |
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79 | |
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80 | EQUATIONS |
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81 | "Component Molar Balance" |
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82 | diff(M)= InletLiquid.F*InletLiquid.z - OutletLiquid.F*OutletLiquid.z - OutletVapour.F*OutletVapour.z; |
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83 | |
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84 | "Energy Balance" |
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85 | diff(E) = InletLiquid.F*InletLiquid.h - OutletLiquid.F*OutletLiquid.h - OutletVapour.F*OutletVapour.h + InletQ; |
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86 | |
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87 | "Molar Holdup" |
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88 | M = ML*OutletLiquid.z + MV*OutletVapour.z; |
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89 | |
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90 | "Energy Holdup" |
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91 | E = ML*OutletLiquid.h + MV*OutletVapour.h - OutletLiquid.P*V; |
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92 | |
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93 | "Mol fraction normalisation" |
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94 | sum(OutletLiquid.z)=1.0; |
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95 | sum(OutletLiquid.z)=sum(OutletVapour.z); |
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96 | |
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97 | "Vapour Density" |
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98 | rhoV = PP.VapourDensity(OutletVapour.T, OutletVapour.P, OutletVapour.z); |
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99 | |
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100 | "Liquid Volume" |
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101 | vL = PP.LiquidVolume(OutletLiquid.T, OutletLiquid.P, OutletLiquid.z); |
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102 | |
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103 | "Vapour Volume" |
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104 | vV = PP.VapourVolume(OutletVapour.T, OutletVapour.P, OutletVapour.z); |
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105 | |
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106 | "Chemical Equilibrium" |
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107 | PP.LiquidFugacityCoefficient(OutletLiquid.T, OutletLiquid.P, OutletLiquid.z)*OutletLiquid.z = PP.VapourFugacityCoefficient(OutletVapour.T, OutletVapour.P, OutletVapour.z)*OutletVapour.z; |
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108 | |
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109 | "Mechanical Equilibrium" |
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110 | OutletLiquid.P = OutletVapour.P; |
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111 | |
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112 | "Thermal Equilibrium" |
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113 | OutletLiquid.T = OutletVapour.T; |
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114 | |
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115 | "Geometry Constraint" |
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116 | V = ML*vL + MV*vV; |
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117 | |
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118 | "Level of liquid phase" |
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119 | Level = ML*vL/Across; |
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120 | |
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121 | end |
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122 | |
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123 | #*---------------------------------------------------------------------- |
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124 | * Model of a Steady State reboiler with no thermodynamics equilibrium |
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125 | *---------------------------------------------------------------------*# |
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126 | Model reboilerSteady |
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127 | ATTRIBUTES |
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128 | Pallete = true; |
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129 | Icon = "icon/ReboilerSteady"; |
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130 | Brief = "Model of a Steady State reboiler with no thermodynamics equilibrium - thermosyphon."; |
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131 | Info = |
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132 | "== Assumptions == |
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133 | * perfect mixing of both phases; |
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134 | * no thermodynamics equilibrium; |
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135 | * no liquid entrainment in the vapour stream. |
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136 | |
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137 | == Specify == |
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138 | * the InletLiquid stream; |
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139 | * the heat supply OR the outlet temperature (OutletVapour.T); |
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140 | "; |
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141 | |
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142 | PARAMETERS |
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143 | outer PP as Plugin (Brief = "External Physical Properties", Type="PP"); |
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144 | outer NComp as Integer; |
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145 | Pdrop as press_delta (Brief="Pressure Drop in the reboiler"); |
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146 | |
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147 | VARIABLES |
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148 | in InletLiquid as stream (Brief="Liquid inlet stream", PosX=0.3345, PosY=1, Symbol="_{inL}"); |
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149 | out OutletVapour as vapour_stream (Brief="Vapour outlet stream", PosX=0.3369, PosY=0, Symbol="_{outV}"); |
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150 | in InletQ as power (Brief="Heat supplied", PosX=1, PosY=0.6111, Symbol="_{in}"); |
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151 | vV as volume_mol (Brief="Vapour Molar volume"); |
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152 | rhoV as dens_mass (Brief="Vapour Density"); |
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153 | |
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154 | EQUATIONS |
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155 | |
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156 | "Molar Flow Balance" |
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157 | InletLiquid.F = OutletVapour.F; |
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158 | |
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159 | "Molar Composition Balance" |
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160 | InletLiquid.z = OutletVapour.z; |
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161 | |
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162 | "Vapour Volume" |
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163 | vV = PP.VapourVolume(OutletVapour.T, OutletVapour.P, OutletVapour.z); |
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164 | |
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165 | "Vapour Density" |
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166 | rhoV = PP.VapourDensity(OutletVapour.T, OutletVapour.P, OutletVapour.z); |
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167 | |
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168 | "Energy Balance" |
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169 | InletLiquid.F*InletLiquid.h + InletQ = OutletVapour.F*OutletVapour.h; |
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170 | |
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171 | "Pressure Drop" |
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172 | OutletVapour.P = InletLiquid.P - Pdrop; |
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173 | |
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174 | end |
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175 | |
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176 | #*---------------------------------------------------------------------- |
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177 | * Model of a Steady State reboiler with fake calculation of |
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178 | * vaporisation fraction and output temperature, but with a real |
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179 | * calculation of the output stream enthalpy |
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180 | *---------------------------------------------------------------------*# |
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181 | Model reboilerSteady_fakeH |
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182 | ATTRIBUTES |
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183 | Pallete = true; |
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184 | Icon = "icon/ReboilerSteady"; |
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185 | Brief = "Model of a Steady State reboiler with fake calculation of outlet conditions."; |
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186 | Info = |
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187 | "Model of a Steady State reboiler with fake calculation of |
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188 | vaporisation fraction and output temperature, but with a real |
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189 | calculation of the output stream enthalpy. |
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190 | "; |
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191 | |
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192 | PARAMETERS |
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193 | outer PP as Plugin(Brief = "External Physical Properties", Type="PP"); |
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194 | outer NComp as Integer; |
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195 | DP as press_delta (Brief="Pressure Drop in the reboiler"); |
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196 | k as Real (Brief = "Flow Constant", Unit='mol/J'); |
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197 | |
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198 | VARIABLES |
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199 | in InletLiquid as stream(Brief="Liquid inlet stream", PosX=0.3345, PosY=1, Symbol="_{inL}"); |
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200 | out OutletVapour as vapour_stream(Brief="Vapour outlet stream", PosX=0.3369, PosY=0, Symbol="_{outV}"); |
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201 | in InletQ as power (Brief="Heat supplied", PosX=1, PosY=0.6111, Symbol="_{in}"); |
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202 | |
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203 | EQUATIONS |
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204 | "Molar Balance" |
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205 | InletLiquid.F = OutletVapour.F; |
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206 | InletLiquid.z = OutletVapour.z; |
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207 | |
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208 | "Energy Balance" |
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209 | InletLiquid.F*InletLiquid.h + InletQ = OutletVapour.F*OutletVapour.h; |
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210 | |
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211 | "Pressure" |
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212 | DP = InletLiquid.P - OutletVapour.P; |
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213 | |
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214 | "Fake Vapourisation Fraction" |
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215 | OutletVapour.v = 1.0; |
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216 | |
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217 | "Fake output temperature" |
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218 | OutletVapour.T = 300*'K'; |
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219 | |
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220 | "Pressure Drop through the reboiler" |
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221 | OutletVapour.F = k*InletQ; |
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222 | end |
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223 | |
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224 | #*------------------------------------------------------------------- |
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225 | * Model of a dynamic reboiler with reaction |
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226 | *-------------------------------------------------------------------*# |
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227 | Model reboilerReact |
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228 | ATTRIBUTES |
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229 | Pallete = false; |
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230 | Icon = "icon/Reboiler"; |
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231 | Brief = "Model of a dynamic reboiler with reaction."; |
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232 | Info = |
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233 | "== Assumptions == |
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234 | * perfect mixing of both phases; |
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235 | * thermodynamics equilibrium; |
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236 | * no liquid entrainment in the vapour stream; |
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237 | * the reaction takes place only in the liquid phase. |
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238 | |
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239 | == Specify == |
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240 | * the kinetics variables; |
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241 | * the inlet stream; |
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242 | * the liquid inlet stream; |
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243 | * the outlet flows: OutletVapour.F and OutletLiquid.F; |
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244 | * the heat supply. |
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245 | |
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246 | == Initial Conditions == |
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247 | * the reboiler temperature (OutletLiquid.T); |
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248 | * the reboiler liquid level (Level); |
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249 | * (NoComps - 1) OutletLiquid (OR OutletVapour) compositions. |
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250 | "; |
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251 | |
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252 | PARAMETERS |
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253 | outer PP as Plugin(Type="PP"); |
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254 | outer NComp as Integer; |
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255 | Across as area (Brief="Cross Section Area of reboiler"); |
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256 | V as volume (Brief="Total volume of reboiler"); |
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257 | |
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258 | stoic(NComp) as Real(Brief="Stoichiometric matrix"); |
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259 | Hr as energy_mol; |
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260 | |
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261 | Initial_Level as length (Brief="Initial Level of liquid phase"); |
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262 | Initial_Temperature as temperature (Brief="Initial Temperature of Reboiler"); |
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263 | Initial_Composition(NComp) as fraction (Brief="Initial Liquid Composition"); |
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264 | |
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265 | VARIABLES |
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266 | in InletLiquid as stream (Brief="Liquid inlet stream", PosX=0, PosY=0.5254, Symbol="_{inL}"); |
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267 | out OutletLiquid as liquid_stream (Brief="Liquid outlet stream", PosX=0.2413, PosY=1, Symbol="_{outL}"); |
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268 | out OutletVapour as vapour_stream (Brief="Vapour outlet stream", PosX=0.5079, PosY=0, Symbol="_{outV}"); |
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269 | InletQ as power (Brief="Heat supplied", PosX=1, PosY=0.6123, Symbol="_{in}"); |
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270 | |
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271 | M(NComp) as mol (Brief="Molar Holdup in the tray"); |
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272 | ML as mol (Brief="Molar liquid holdup"); |
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273 | MV as mol (Brief="Molar vapour holdup"); |
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274 | E as energy (Brief="Total Energy Holdup on tray"); |
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275 | vL as volume_mol (Brief="Liquid Molar Volume"); |
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276 | vV as volume_mol (Brief="Vapour Molar volume"); |
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277 | Level as length (Brief="Level of liquid phase"); |
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278 | Vol as volume; |
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279 | rhoV as dens_mass; |
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280 | r3 as reaction_mol (Brief = "Reaction resulting ethyl acetate", DisplayUnit = 'mol/l/s'); |
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281 | C(NComp) as conc_mol (Brief = "Molar concentration", Lower = -1); |
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282 | |
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283 | INITIAL |
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284 | |
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285 | Level = Initial_Level; |
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286 | OutletLiquid.T = Initial_Temperature; |
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287 | OutletLiquid.z(1:NComp-1) = Initial_Composition(1:NComp-1)/sum(Initial_Composition); |
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288 | |
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289 | EQUATIONS |
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290 | "Molar Concentration" |
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291 | OutletLiquid.z = vL * C; |
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292 | |
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293 | "Reaction" |
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294 | r3 = exp(-7150*'K'/OutletLiquid.T)*(4.85e4*C(1)*C(2) - 1.23e4*C(3)*C(4)) * 'l/mol/s'; |
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295 | |
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296 | "Component Molar Balance" |
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297 | diff(M)= InletLiquid.F*InletLiquid.z- OutletLiquid.F*OutletLiquid.z - OutletVapour.F*OutletVapour.z + stoic*r3*ML*vL; |
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298 | |
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299 | "Energy Balance" |
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300 | diff(E) = InletLiquid.F*InletLiquid.h- OutletLiquid.F*OutletLiquid.h - OutletVapour.F*OutletVapour.h + InletQ + Hr * r3 * vL*ML; |
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301 | |
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302 | "Molar Holdup" |
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303 | M = ML*OutletLiquid.z + MV*OutletVapour.z; |
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304 | |
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305 | "Energy Holdup" |
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306 | E = ML*OutletLiquid.h + MV*OutletVapour.h - OutletLiquid.P*V; |
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307 | |
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308 | "Mol fraction normalisation" |
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309 | sum(OutletLiquid.z)=1.0; |
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310 | |
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311 | "Liquid Volume" |
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312 | vL = PP.LiquidVolume(OutletLiquid.T, OutletLiquid.P, OutletLiquid.z); |
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313 | |
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314 | "Vapour Volume" |
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315 | vV = PP.VapourVolume(OutletVapour.T, OutletVapour.P, OutletVapour.z); |
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316 | |
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317 | "Vapour Density" |
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318 | rhoV = PP.VapourDensity(OutletVapour.T, OutletVapour.P, OutletVapour.z); |
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319 | |
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320 | "Level of liquid phase" |
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321 | Level = ML*vL/Across; |
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322 | |
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323 | Vol = ML*vL; |
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324 | |
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325 | "Mechanical Equilibrium" |
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326 | OutletLiquid.P = OutletVapour.P; |
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327 | |
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328 | "Thermal Equilibrium" |
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329 | OutletLiquid.T = OutletVapour.T; |
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330 | |
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331 | "Geometry Constraint" |
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332 | V = ML*vL + MV*vV; |
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333 | |
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334 | "Chemical Equilibrium" |
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335 | PP.LiquidFugacityCoefficient(OutletLiquid.T, OutletLiquid.P, OutletLiquid.z)*OutletLiquid.z = |
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336 | PP.VapourFugacityCoefficient(OutletVapour.T, OutletVapour.P, OutletVapour.z)*OutletVapour.z; |
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337 | |
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338 | sum(OutletLiquid.z)=sum(OutletVapour.z); |
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339 | |
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340 | end |
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341 | |
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342 | Model reboiler |
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343 | |
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344 | ATTRIBUTES |
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345 | Pallete = true; |
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346 | Icon = "icon/Reboiler"; |
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347 | Brief = "Model of a dynamic reboiler - kettle with control."; |
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348 | Info = |
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349 | "== ASSUMPTIONS == |
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350 | |
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351 | * perfect mixing of both phases; |
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352 | * thermodynamics equilibrium; |
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353 | * no liquid entrainment in the vapour stream. |
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354 | |
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355 | == SPECIFY == |
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356 | |
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357 | * the InletLiquid stream; |
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358 | * the outlet flows: OutletVapour.F and OutletLiquid.F; |
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359 | * the InletQ (the model requires an energy stream, also you can use a controller for setting the heat duty using the heat_flow model). |
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360 | |
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361 | == OPTIONAL == |
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362 | * the reboiler model has three control ports |
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363 | ** TI OutletLiquid Temperature Indicator; |
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364 | ** PI OutletLiquid Pressure Indicator; |
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365 | ** LI Level Indicator of Reboiler; |
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366 | |
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367 | == INITIAL CONDITIONS == |
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368 | |
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369 | * Initial_Temperature : the reboiler temperature (OutletLiquid.T); |
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370 | * Initial_Level : the reboiler liquid level (Level); |
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371 | * Initial_Composition : (NoComps) OutletLiquid compositions. |
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372 | "; |
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373 | |
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374 | PARAMETERS |
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375 | outer PP as Plugin (Brief = "External Physical Properties", Type="PP"); |
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376 | outer NComp as Integer (Brief="Number of Components"); |
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377 | Across as area (Brief="Cross Section Area of reboiler"); |
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378 | V as volume (Brief="Total volume of reboiler"); |
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379 | |
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380 | Initial_Level as length (Brief="Initial Level of liquid phase"); |
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381 | Initial_Temperature as temperature (Brief="Initial Temperature of Reboiler"); |
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382 | Initial_Composition(NComp) as positive (Brief="Initial Liquid Composition",Lower=1E-6); |
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383 | |
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384 | VARIABLES |
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385 | |
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386 | in InletLiquid as stream (Brief="Liquid inlet stream", PosX=0.17, PosY=1, Symbol="_{in}^{Liquid}"); |
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387 | out OutletLiquid as liquid_stream (Brief="Liquid outlet stream", PosX=0.53, PosY=1, Symbol="_{out}^{Liquid}"); |
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388 | out OutletVapour as vapour_stream (Brief="Vapour outlet stream", PosX=0.17, PosY=0, Symbol="_{out}^{Vapour}"); |
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389 | in InletQ as power (Brief="Heat supplied", Protected = true, PosX=1, PosY=0.08, Symbol="Q_{in}"); |
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390 | |
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391 | out TI as control_signal (Brief="Temperature Indicator of Reboiler", Protected = true, PosX=0.44, PosY=0); |
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392 | out LI as control_signal (Brief="Level Indicator of Reboiler", Protected = true, PosX=0.53, PosY=0); |
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393 | out PI as control_signal (Brief="Pressure Indicator of Reboiler", Protected = true, PosX=0.35, PosY=0); |
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394 | |
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395 | M(NComp) as mol (Brief="Molar Holdup in the tray", Protected = true); |
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396 | ML as mol (Brief="Molar liquid holdup", Protected = true); |
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397 | MV as mol (Brief="Molar vapour holdup", Protected = true); |
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398 | E as energy (Brief="Total Energy Holdup on tray", Protected = true); |
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399 | vL as volume_mol (Brief="Liquid Molar Volume", Protected = true); |
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400 | vV as volume_mol (Brief="Vapour Molar volume", Protected = true); |
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401 | rhoV as dens_mass (Brief="Vapour Density", Protected = true, Symbol="\rho"); |
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402 | Level as length (Brief="Level of liquid phase", Protected = true); |
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403 | Pdrop as press_delta (Brief = "Pressure Drop", DisplayUnit = 'kPa', Symbol ="\Delta P", Protected=true); |
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404 | |
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405 | INITIAL |
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406 | |
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407 | "Initial Level" |
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408 | Level = Initial_Level; |
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409 | |
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410 | "Initial Temperature" |
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411 | OutletLiquid.T = Initial_Temperature; |
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412 | |
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413 | "Initial Composition" |
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414 | OutletLiquid.z(1:NComp-1) = Initial_Composition(1:NComp-1)/sum(Initial_Composition); |
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415 | |
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416 | EQUATIONS |
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417 | |
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418 | "Component Molar Balance" |
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419 | diff(M)= InletLiquid.F*InletLiquid.z - OutletLiquid.F*OutletLiquid.z - OutletVapour.F*OutletVapour.z; |
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420 | |
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421 | "Energy Balance" |
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422 | diff(E) = InletLiquid.F*InletLiquid.h - OutletLiquid.F*OutletLiquid.h - OutletVapour.F*OutletVapour.h + InletQ; |
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423 | |
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424 | "Molar Holdup" |
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425 | M = ML*OutletLiquid.z + MV*OutletVapour.z; |
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426 | |
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427 | "Energy Holdup" |
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428 | E = ML*OutletLiquid.h + MV*OutletVapour.h - OutletLiquid.P*V; |
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429 | |
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430 | "Mol Fraction Normalisation" |
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431 | sum(OutletLiquid.z)=1.0; |
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432 | |
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433 | "Mol fraction Constraint" |
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434 | sum(OutletLiquid.z)=sum(OutletVapour.z); |
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435 | |
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436 | "Vapour Density" |
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437 | rhoV = PP.VapourDensity(OutletVapour.T, OutletVapour.P, OutletVapour.z); |
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438 | |
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439 | "Liquid Volume" |
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440 | vL = PP.LiquidVolume(OutletLiquid.T, OutletLiquid.P, OutletLiquid.z); |
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441 | |
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442 | "Vapour Volume" |
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443 | vV = PP.VapourVolume(OutletVapour.T, OutletVapour.P, OutletVapour.z); |
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444 | |
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445 | "Chemical Equilibrium" |
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446 | PP.LiquidFugacityCoefficient(OutletLiquid.T, OutletLiquid.P, OutletLiquid.z)*OutletLiquid.z = PP.VapourFugacityCoefficient(OutletVapour.T, OutletVapour.P, OutletVapour.z)*OutletVapour.z; |
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447 | |
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448 | "Mechanical Equilibrium" |
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449 | OutletLiquid.P = OutletVapour.P; |
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450 | |
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451 | "Thermal Equilibrium" |
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452 | OutletLiquid.T = OutletVapour.T; |
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453 | |
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454 | "Pressure Drop" |
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455 | OutletLiquid.P = InletLiquid.P - Pdrop; |
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456 | |
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457 | "Geometry Constraint" |
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458 | V = ML*vL + MV*vV; |
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459 | |
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460 | "Level of liquid phase" |
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461 | Level = ML*vL/Across; |
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462 | |
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463 | "Temperature Indicator" |
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464 | TI * 'K' = OutletLiquid.T; |
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465 | |
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466 | "Pressure Indicator" |
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467 | PI * 'atm' = OutletLiquid.P; |
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468 | |
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469 | "Level indicator" |
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470 | LI*V = Level*Across; |
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471 | |
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472 | end |
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